Relationship between metal-metal bond length and internal rotation in diruthenium tetracarboxylate paddlewheel complexes.
نویسندگان
چکیده
The Ru-Ru bond length for Ru2II,III and Ru2II,II paddlewheel complexes containing the bulky carboxylate ligand 2,4,6-triisopropylbenzoate was found to decrease despite a reduction in Ru-Ru bond order, due to increased internal rotation.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 2 شماره
صفحات -
تاریخ انتشار 2009